Homework #4

Chapter 3:
                        31, 32, 33, 34, 36, 37, 38, 40, 42




Hints/comments:

3.37: Note that after removal from the bath both the frozen and liquid benzene are still at 5.5 deg. C.

3.40: There are a couple of ways to do this. In general what you need to do is integrate Cp(T) dT/T from 0 to 172.12 K. Use a cubic function for Cp(T) between 0 K and the lowest temperature data point and then either fit the remaining data to a polynomial function or interpolate it with a program like MathCad. Then integrate. Remember not to use the point at 172.12 K where Cl2 melts and Cp(T) is discontinuous. The solution manual value is So = 107.75 J K-1 mol-1. Note: I obtain 108.0 J K-1 mol-1 using a polynomial fit to Cp.